Water Pre-Treatment

Raw water quality depends greatly on its source. Based on the raw water quality and the specifications for the purified water, Centec select the most appropriate technologies for each client. Usually, multi-stage regimes are necessary for water purification. For water pre-treatment, sand and multi media filters are used to remove suspended material (e. g. silt, clay, organic matter). Such material in water can reduce the effectiveness of downstream components such as ion exchange resins and reverse osmosis membranes. Soluble iron and manganese are found in water that contains no dissolved oxygen. They cause a metallic taste and form deposits in piping systems. The Centec De-Ironizer is designed for iron and manganese removal. If harmful bacteria and microbes are suspected, the water is disinfected by UV, ozone or free chlorine. Activated carbon (AC) filtration removes odours, tastes and oxidizing agents like free chlorine that can lead to chemical attack of membranes elements in subsequent purification steps.

A sand filter only uses sand as filter medium. Whereas a multi media filter typically have 3 to 5 layers of different media types. Both are back-flushable. In a sand filter the smallest particles are trapped at the top of the media bed, while larger ones sink deeper proportional to their mass. The result is a very limited use of the media depth, because virtually all filterable particles are trapped at the very top of the filter bed. Multi media filters use several layers of different materials, each having a significantly different density. Due to the layering, larger particles are removed first at the top of the media bed, while smaller particles are trapped further below. Trapping particles in this manner, results in more effective removal of contaminants, even of very small turbidity forming particles. Furthermore, longer run times between backwash cycles are achieved.

Dissolved iron and manganese are removed from water by oxidation and subsequent filtration. Fe²⁺ is oxidized to Fe³⁺, which with oxygen, forms the insoluble iron complex Fe(OH)₃. Mn²⁺ is oxidized to Mn⁴⁺, which with oxygen, forms insoluble MnO₂. An ideal and low-cost method of providing oxidation is to use the oxygen in air as the oxidizing agent. For removal of the insoluble iron and manganese gravel can serve as filtration media. By cyclical back-flushing the iron and manganese particles are washed out and removed.

Activated carbon filtration is a method of filtering that uses a bed of activated carbon to remove contaminants by chemical absorption. Due to the highly porous structure of activated carbon, each carbon particle provides an extremely large surface area. Contaminant molecules are trapped inside this structure. Activated carbon adsorbs organic substances which cause odours and tastes. Furthermore, it acts as a catalyst in contact with free chlorine supporting the reaction of free chlorine to harmless chloride ions.

Chlorine is an inexpensive treatment method for deactivating microorganisms like bacteria and viruses. Stored in pressurized containers, it can be injected as a gas directly into the water. Alternatively, a sodium hypochlorite solution can be used. This solution is easier to handle than chlorine gas. Disinfection can also be achieved with calcium hypochlorite, a solid disinfectant. This form can be stored as powders, granules or tablets. Ozone (O₃) is another powerful oxidizing agent. It is pumped into water systems to kill biological contaminants like bacteria and viruses. Since ozone gas is very unstable, O₃ needs to be created on site. Ozone is pure active oxygen and produces no residual odours or tastes in water. Also ultraviolet (UV) light can be used to kill harmful microorganisms. The UV process is an attractive option in many cases because it is chemical-free and investment costs are low.